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Question

It is found that the equilibrium constant increases by a factor of four when the temperature is increased from 27 C to 47 C. The value of ΔH is:
Take ln2=0.7, log2=0.3, R=253 J mol1 K1

A
28 kJ/mol
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B
12 kJ/mol
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C
24 kJ/mol
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D
56 kJ/mol
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Solution

The correct option is D 56 kJ/mol
Using the equation,
ln(Kp)47 C(Kp)27 C=ΔHR[1T11T2]

We get,
ln 4=ΔH25/3(1273+271273+47)

ΔH=56 kJ/mol

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