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Question

IUPAC name of Na3[Co(NO2)6] is

A
sodium cobaltinitrite
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B
sodium hexanitritocobaltate (III)
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C
trisodium hexanitritoocobalt (III)
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D
sodium hexanitritocobaltate (II)
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Solution

The correct option is B sodium hexanitritocobaltate (III)
Cobalt exists in +3 oxidation state, and the complex is negatively charged, so the metal name should end in -ate.

The answer is sodium hexanitritocobaltate (III)

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