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Question

IUPAC name of the compound is ____________.


A
2methoxy2methylethane
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B
2methoxypropane
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C
isopropylmethyl ether
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D
1methoxy1methylethane
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Solution

The correct option is B 2methoxypropane
IUPAC nomenclature of the given compound

Following are some important rules for naming ether:
  1. The alkoxy group with shorter carbon chain is taken as substituent and the longest carbon chain is taken as parent chain.
  2. While numbering, the carbon closest to oxygen is given more priority.
  3. Ethers are named as "alkoxyalkane". Oxygen of ether is taken with the substituent (or with shorter chain) and forms a part of alkoxy group whereas alkane part is considered as the parent chain.

So, the correct IUPAC name will be 2methoxypropane

Analysing the options

Option (A):

1methoxy1methylethane is not the correct IUPAC name of the given compound because the parent chain is not the longest carbon chain.

Option (B):

2methoxy2methylethane is also not the correct IUPAC name because in this the parent chain is not the longest carbon chain.

Option (C):

2methoxypropane is the correct IUPAC name as discussed before.

Option (D):

Isopropylmethyl ether is the common name of given compound.

So, the correct answer is option (C).

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