Pair of equations is
2x+3y−5=0 ...(i)
px−6y−8=0 ...(ii)
Pair of equations have unique solution if
a1a2≠b1b2
Here, a1=2, b1=3 and
a2=p,b2=−6
⇒2p≠3−6
⇒3p≠−2×6
⇒p≠−123
⇒p≠−4
Hence, the system of linear equations has unique solution for all real values of p except -4.