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Question

K3[Fe(CN)6] is used in the detection of Fe2+ ion which it gives a deep blue colour. This colour is due to the formation of:

A
K2Fe[Fe(CN)6]
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B
Fe4[Fe(CN)6]3
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C
Fe[Fe(CN)6]
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D
Fe3[Fe(CN)6]2
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Solution

The correct option is B Fe3[Fe(CN)6]2
The reaction of Fe2+ with potassium ferricyanide forms blue precipitate of Turnbull's blue which is used as pigment in ink and paint.
3Fe2++2K3[Fe(CN)6]Fe3[Fe(CN)6]2

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