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Question

Ka for CH3COOH at 25oC is 1.754×105. What are So in J/mol.K for the ionisation of CH3COOH if Ho is 1.55 kJ/mol?
log(1.754 ) = 0.244

A
-96.44
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B
96.26
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C
50.56
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D
17.54
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Solution

The correct option is A -96.44
we know the relation
(Go)298=2.303RT log K
=2.303×8.314×298×log(1.754×105)
=2.303×8.314×298×(5+log(1.754)
=2.303×8.314×298×(5+0.244)
=2.303×8.314×298×4.756
=27137 J.
Go=HoTSo
27137.01=1550298 So
S0=96.265 J/mol.K

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