KP=0.04atm at 899K for the equilibrium shown below. What is the equilibrium concentration of C2H6 when it is placed in a flask at 4.0atm pressure and allowed to come to equilibrium? C2H6(g)⇌C2H6(g)+H2(g) :
A
7.24atm
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B
3.62atm
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C
1atm
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D
1.5atm
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Solution
The correct option is B3.62atm The equilibrium reaction is
C2H6(g)⇌C2H4(g)+H2(g).
Initial
4
0
0
Change
−x
x
x
Equilibrium
4−x
x
x
The expression for the equilibrium constant is Kp=PC2H4PH2PC2H6. Substitute values in the above expression. 0.04=x24−x or x=0.38
Thus the pressure of ethane is, PC2H6=3.62atm. Option B is correct.