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Question

KP=0.04atm at 899K for the equilibrium shown below. What is the equilibrium concentration of C2H6 when it is placed in a flask at 4.0atm pressure and allowed to come to equilibrium?
C2H6(g)C2H6(g)+H2(g) :

A
7.24atm
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B
3.62atm
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C
1atm
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D
1.5atm
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Solution

The correct option is B 3.62atm
The equilibrium reaction is
C2H6(g)C2H4(g)+H2(g).


Initial
4
0
0
Change
x
x
x
Equilibrium 4x
x
x
The expression for the equilibrium constant is Kp=PC2H4PH2PC2H6.
Substitute values in the above expression.
0.04=x24x or x=0.38

Thus the pressure of ethane is, PC2H6=3.62atm.
Option B is correct.

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