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Question

KCIO4 may be made by means of the following series of reactions:
CI2+2KOHKCI+KCIO+H2O
3KCIO2KCI+KCIO3
4KCIO33KCI4+KCI
How much CI2 is needed to prepare 200 g KCLO4 by the above sequence?

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Solution

The arrangement of conditions includes;

Cl2+2KOHKCl+KClO+H2O......(1)

3KClO2KCl+KClO3......(2)

4KClO33KClO4+KCl.......(3)

From the eqn(3)

The proportion KClO4KCl=31

Implying that we have 3 moles of KClO3

We have 1mole of KCl

Since the molar mass of KClO4 is 138.55,

We have =156138.55

Moles delivered =1.126moles

On the off chance that we accept 100% yield these originated from (1.125×43) moles of KClO3

=1.501 moles of KClO3 required to deliver 156g of KClO4

Moles of KClO expected to deliver 1.501 moles of KClO3

=1.501×3=4.504 moles of KClO from eqn(2)

From eqn(1)

Moles of Cl2=moles of KClO =4.504 moles.

Along these lines, the mass of Cl2=4.504×71

Mass of Cl2=319g to deliver 156g of KClO4 if 100% yield is accepted in the three compound responses.

Hence, this is the answer.


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