Kjeldahl's method was used for the estimation of nitrogen in an organic compound. The ammonia evolved from 0.55g of the compound neutralised 12.5mL of 1MH2SO4 solution. The percentage of nitrogen in the compound is (Nearest integer)
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Solution
Meq. of H2SO4 = Meq. of NH3
12. 5 × 1 × 2 = 25 meq. of NH3
= 25 millimoles of NH3.
So Millimoles of 'N' = 25
Moles of 'N' = 25×10–3
wt. of N = 14×25×10–3