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Question

Kjeldahl's method was used for the estimation of nitrogen in an organic compound. The ammonia evolved from 0.55 g of the compound neutralised 12.5 mL of 1 M H2SO4 solution. The percentage of nitrogen in the compound is (Nearest integer)

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Solution

Meq. of H2SO4 = Meq. of NH3
12. 5 × 1 × 2 = 25 meq. of NH3
= 25 millimoles of NH3.
So Millimoles of 'N' = 25
Moles of 'N' = 25×103
wt. of N = 14×25×103

% N=1.4×N×VMass of organic compound

=1.4×2×12.50.55=63.63% 64



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