The correct option is B MnO2
Potassium permanganate forms dark purple (almost black) crystals which are isostructural with those of KClO4 . The salt is not very soluble in water (6.4 g/100 g of water at 293 K), but when heated it decomposes at 513 K.
2KMnO4Δ−→K2MnO4+MnO2+O2
Hence, option (a) and (b) are correct.