KMnO4 reacts with oxalic acid according to the equation, 2MnO−4+5C2O2−4+16H+→2Mn2++10CO2+8H2O Here, 20 mL of 0.1 M KMnO4 is equivalent to:
A
20 mL of 0.5 M H2C2O4
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B
50 mL of 0.1 M H2C2O4
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C
50 ml of 0.01 M H2C2O4
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D
20 ml of 0.1 M H2C2O4
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Solution
The correct option is B 50 mL of 0.1 M H2C2O4 50 mL of 0.1 M H2C2O4 Equivalents of MnO4− = Equivalents of C2O2−4 M×V×nf=M×V×nf (0.1)×(20)×5=(50)×(0.1)×2 10=10