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Byju's Answer
Standard XII
Chemistry
Kohlrausch Law
λ∞ of NH4OH...
Question
λ
∞
of
N
H
4
O
H
at infinite dilution is ______
S
c
m
2
m
o
l
−
1
given
λ
∞
of
O
H
−
=
174
,
λ
∞
if
C
l
−
=
66
and
λ
∞
of
N
H
4
C
l
=
130
S
c
m
2
m
o
l
−
1
A
140
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B
218
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C
238
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D
198
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Solution
The correct option is
C
238
λ
∞
N
H
4
O
H
=
λ
∞
N
H
+
4
+
λ
∞
O
H
(
−
)
=
(
λ
∞
N
H
4
C
l
−
λ
∞
C
l
(
−
)
)
+
λ
∞
O
H
(
−
)
=
130
−
66
+
174
=
238
s
c
m
2
m
o
l
−
1
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0
Similar questions
Q.
The degree of dissociation of 2.5 × 10
–2
M methanoic acid solution having molar conductivity 46.1 S cm
2
mol
–1
will be (Given : λ°(H
+
) = 349.6 S cm
2
mol
–1
and λ°(HCOO
–
) = 54.6 S cm
2
mol
–1
)
मोलर चालकता 46.1 S cm
2
mol
–1
वाले 2.5 × 10
–2
M मेथनॉइक अम्ल विलयन के वियोजन की मात्रा होगी (दिया है: λ°(H
+
) = 349.6 S cm
2
mol
–1
तथा λ°(HCOO
–
) = 54.6 S cm
2
mol
–1
)
Q.
The values of equivalent conductivity at infinite dilutions for
N
H
4
C
l
,
N
a
O
H
and
N
a
C
l
are respectively
149.74
,
248.1
and
126.4
o
h
m
−
1
c
m
2
e
q
u
i
−
1
. The value of
λ
−
e
q
of
N
H
4
O
H
is?
Q.
At 298 K the molar conductivities at infinite dilution (
Λ
∘
m
) of
N
H
4
C
l
,
K
O
H
and
K
C
l
are 152.8, 272.6 and 149.8
S
c
m
2
m
o
l
−
1
respectively. The
Λ
∘
m
of
N
H
4
O
H
in
S
c
m
2
m
o
l
−
1
and % dissociation of 0.01 M
N
H
4
O
H
with
Λ
m
=
25.1
S
c
m
2
m
o
l
−
1
at the same temperature are:
Q.
(a) The conductivity of 0.001
m
o
l
L
−
1
solution of
C
H
3
C
O
O
H
is
3.905
×
10
−
5
S
c
m
−
1
.
Calculate its molar conductivity and degree of dissociation
α
.
Given
λ
∘
(
H
+
)
=
349.6
S
c
m
2
m
o
l
−
1
and
λ
∘
(
C
H
3
C
O
O
−
)
=
40.9
S
c
m
2
m
o
l
−
1
.
(b) Define electrochemical cell. What happens if external potential applied becomes greater than
E
∘
c
e
l
l
of electrochemical cell?
Q.
Given the following molar conductivity at infinite dilution and
25
o
C
HCl:
∧
∞
m
=
426.2
S
c
m
2
m
o
l
−
1
KCl:
∧
∞
m
= 114.42 S
c
m
2
m
o
l
−
1
C
H
3
C
O
O
K
:
∧
∞
m
=
149.86
S
c
m
2
m
o
l
−
1
The molar conductance at infinite dilution and
25
o
C, for acetic acid solution is:
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