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Question

Lanthanide contraction is due to increase in:

A
shielding by 4f electrons
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B
atomic number
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C
effective nuclear charge
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D
size of 4 f-orbital
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Solution

The correct option is C effective nuclear charge
Lanthanoid contraction effect results from poor shielding of nuclear charge (nuclear attractive force on electrons) by 4f electrons so effective nuclear charge increases; the 6s electrons are drawn towards the nucleus, thus resulting in a smaller atomic radius.

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