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Question

Law of mass action cannot be applied to:

A
decomposition of gaseous HI
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B
decomposition of gaseous PCl5
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C
transition of Rhombic Sulphur to Monoclicnic sulphur
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D
decomposition of Calcium carbonate
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Solution

The correct option is D transition of Rhombic Sulphur to Monoclicnic sulphur
The transition of Rhombic sulphur to monoclinic sulphur is not a chemical reaction since the chemical species sulphur remains the same. It only change from one allotropic form to the other.

Hence, law of mass action cannot be applied.

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