First law of thermodynamics: When energy passes, as work, as heat, or with matter, into or out from a system, the system'sinternal energy changes in accord with the law of conservation of energy. Equivalently,perpetual motion machines of the first kind(machines that produce work with no energy input) are impossible.
Second law of thermodynamics: In a naturalthermodynamic process, the sum of theentropies of the interacting thermodynamic systems increases. Equivalently, perpetual motion machines of the second kind(machines that spontaneously convert thermal energy into mechanical work) are impossible.
Third law of thermodynamics: The entropyof a system approaches a constant value as the temperature approaches absolute zero. With the exception of non-crystalline solids (glasses) the entropy of a system at absolute zero is typically close to zero, and is equal to the natural logarithm of the product of the quantum ground states.