$[C o {(N H_{3})}_{4} {C l}_{2}] N O_{2}$ and $[C o {(N H_{3})}_{4} C l N O_{2}] C l$ are :

geometrical isomers

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optical isomers

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linkage isomers

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ionisation isomers

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Solution

The correct option is B ionisation isomers
Option (D) is correct.
$[C o {(N H_{3})}_{4} {C l}_{2}] N O_{2}$ and $[C o {(N H_{3})}_{4} C l N O_{2}] C l$ are ionisation isomer.
Ionization isomers are coordination compounds that have 2 different ligands swapped between the inner and the outer coordination spheres.
In the above complex , since the chloride and nitrite ligands have got mutually swapped and are ionization isomers.

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N O_{2}

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