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Question

Let the solubilities of AgCl in pure water, 0.01 M CaCl2, 0.01 M NaCl % 0.05 M AgNO3 be s1,s2,s3 & s4 respectively. What is the correct order of these quantities ? Neglect any complexation.

A
s1>s4>s3>s2
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B
s1>s2=s3>s4
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C
s1>s3>s2>s4
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D
s4>s2>s3>s1
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Solution

The correct option is C s1>s3>s2>s4
Given
Conc. of CaCl2 is 0.01
Conc. of NaCl is 0.01
Conc. of Ag2NO3 is 0.05
Solution
Solubility is inversely proportion to conc. of common ion.
Therefore Water Have most solubility because there is no common ion
AgNO3 have least solubility because highest conc. of Ag ion (0.05)
CaCl2 is less soluble than NaCl because it produces moreClion.
The correct answer is C

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