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Question

Li2SO4 is not isomorphous with sodium sulphate, due to:

A
small size of lithium
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B
high coordination number of lithium
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C
high ionization energy of lithium
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D
none of the above
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Solution

The correct option is A small size of lithium
Isomorphic compounds have same crystal structure at given temperature and conditions. While LiSO4 and Na2SO4 are not isomorphous due to the exceptionally small size of Lithium (Li).

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