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Reactivity with Halogens and Hydrogen (Group 2)

LiF is least ...

Question

LiF is least soluble among the fluorides of alkali metals.

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Solution

LiF is least soluble among the fluorides of alkali metals. For alkali metal fluorides, the solubility in water increases from lithium to caesium.
Alkali metal fluoride
LiF
NaF
KF
RbF
CsF
Solubility in water (g/L)
2.7
42
1020
1310
3700

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