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Question

Light of wavelength 12818˚A is emitted when the electron of a hydrogen atom drops from 5th to 3rd orbit. Find the wavelength of the photon emitted when the electron falls from 3rd to 2nd orbit.

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Solution

We know that,
1λ=R[1n211n22]
When, n1=3 and n2=5,
112818=R[19125]=16R9×25
or 12818=9×2516×R ...(i)
When, n1=2 and n2=3,
1λ=R[1419]=5R36
λ=365R ....(ii)
Dividing equation (ii) by equation (i),
λ12818=365R×16R9×25=64125
λ=64125×12818=6562.8˚A.

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