The correct option is
C P−4,Q−3,R−2,S−1Ag2CrO4: Silver chromate : It is scarlet red in color.
Cu2[Fe(CN)6]: It has a octahedral geometry of iron. and it is chocolate brown in color.
BaSO4: The precipitate of barium sulfate is white in color.
PbI2: Lead II iodide forms a bright yellow odorless crystalline solid , that becomes orange and red when heated.