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Byju's Answer
Standard XII
Chemistry
Third Law of Thermodynamics
log K p / K c...
Question
log
K
p
K
c
+
log
R
T
=
0
is a relationship for the reaction
A
P
C
l
5
(
g
)
⇋
P
C
l
3
(
g
)
+
C
l
2
(
g
)
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B
2
S
O
2
(
g
)
+
O
2
(
g
)
⇋
2
S
O
3
(
g
)
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C
H
2
(
g
)
+
I
2
(
g
)
⇋
2
H
I
(
g
)
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D
N
2
(
g
)
+
3
H
2
(
g
)
⇋
2
N
H
3
(
g
)
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Solution
The correct option is
B
2
S
O
2
(
g
)
+
O
2
(
g
)
⇋
2
S
O
3
(
g
)
We know,
K
p
=
K
C
(
R
T
)
△
n
g
So,
l
o
g
K
p
=
l
o
g
K
C
(
R
T
)
△
n
g
⇒
l
o
g
K
p
−
l
o
g
K
C
=
△
n
g
l
o
g
(
R
T
)
log
K
P
K
C
=
△
n
g
log
R
T
So, according to the question
△
n
g
=
−
1
Hence, for the reaction
2
S
O
2
+
O
2
⇋
2
S
O
3
△
n
g
=
n
p
−
n
R
=
2
−
3
=
−
1
Suggest Corrections
2
Similar questions
Q.
log
K
P
K
C
+
log
R
T
=
0
is a relationship for the reaction:
Q.
In which one of the following reactants,
K
p
is less than
K
c
?
Q.
For which of the following reactions, the degree of dissociation cannot be calculated from the vapour density data
I.
2
H
I
(
g
)
⟶
H
2
(
g
)
+
I
2
(
g
)
II.
2
N
H
3
(
g
)
⟶
N
2
(
g
)
+
3
H
2
(
g
)
III.
2
N
O
(
g
)
⟶
N
2
(
g
)
+
O
2
(
g
)
IV.
P
C
l
5
(
g
)
⟶
P
C
l
3
(
g
)
+
C
l
2
(
g
)
Q.
For which of the following
Δ
H
is not equal to
Δ
U
Q.
The
K
P
K
C
ratio will be highest in case of
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