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B
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C
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D
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Solution
The correct option is B The given reaction undergoes dehydration. Mechanism: Step 1- Formation of carbocation: Here the lone pair of electrons on hydroxyl group will abstract the H+ ion and remove as water molecule leaving behind 1∘ carbocation.
Step 2- Hydrogen shift: From primary carbocation is less stable so the H atom in adjacent carbon get shifted to give a relatively stable 2∘ carbocation.
Step 3- β Elimination Now the secondary carbocation undergo β elimination to form exocyclic double bond as major product because it is stabilised by 7α−Hydrogens. Hence, the major product is (b).