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Question


Major product for the above reaction is :

A
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B
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C
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D
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Solution

The correct option is B
The given reaction undergoes dehydration.
Mechanism:

Step 1- Formation of carbocation:
Here the lone pair of electrons on hydroxyl group will abstract the H+ ion and remove as water molecule leaving behind 1 carbocation.


Step 2- Hydrogen shift:
From primary carbocation is less stable so the H atom in adjacent carbon get shifted to give a relatively stable 2 carbocation.



Step 3- β Elimination
Now the secondary carbocation undergo β elimination to form exocyclic double bond as major product because it is stabilised by 7αHydrogens.
Hence, the major product is (b).




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