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Question

Maleic acid is stronger than fumaric acid because ?

A
Fumaric acids shows intermolecular H-bonding
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B
Fumaric acids shows intermolecular ionic bonding
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C
Meleic acid is disasic acid
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D
Meleic acid shows chelation or intramolecular H-bonding
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Solution

The correct options are
A Fumaric acids shows intermolecular H-bonding
D Meleic acid shows chelation or intramolecular H-bonding

Maleic acid, being a cis-isomer is capable of forming intra-hydrogen bond after losing H+ ion, making the conjugate base much stable than the trans form (fumaric acid) because both the oxygen atoms have strong interaction with the remaining H-atom.
(Refer to Image)

Hence, Aand D are the correct options.

1214517_1127922_ans_8c81795cd93a4ae9900944ed318c11ef.PNG

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