Markovnikov's rule is applicable to Ch2=ch2 Ch3-ch2-ch3 Ch3-ch=ch-ch3 (Ch3) 2-c=c-(ch3) (c2h5)

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H_{3} C - C H_{2} - C H_{3} | C = C H - C | H C_{2} H_{5} - C H_{3} | C H - C H_{2} - C H_{2} - C H_{3}

C H_{3} - C H_{2} - C H_{2} - C H_{2} - C H | C H_{3} - C | C H_{3} - C H_{3} - C H_{2} - C H_{3} | C H - C H_{2} - C H_{2} - C H_{2} - C H_{3}

C H_{3} - C H_{3}, C H_{2} = C H_{2}

C H \equiv C H

A . C H_{3} - C H = C H_{2} + H C l ⟶ C H_{3} - C | C l H - C H_{3}

B . C H_{3} - C H = C H_{2} + H B r ⟶ C H_{3} - C H_{2} - C H_{2} B r

C . C H_{3} - C H = C H_{2} + H B r p e r o x i d e - ---- \to C H_{3} - C H_{2} - C H_{2} - B r

D . C H_{3} - C H = C H_{2} + H I p e r o x i d e - ---- \to C H_{3} - C | I H - C H_{3}

$C H_{3} - C | C H_{2} - C H_{3} = C H - C H_{2} - C H_{2} - C H_{3}$

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