Mass numbers of two isotopes of an element differ by 2 units (A and A+2). Average atomic mass is 0.5 more than the lower mass number. What could be the ratio of the percentage abundance two isotopes respectively?
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Solution
Mass number of Isotope 1=A
Mass number of Isotope 2=A+2 {Both differ by two units}
Average atomic mass= A+0.5
Ration of percentage abundance of two isotopes= ?
Formula:- Let percentage abundance be x & 100−x for A and A+2 respectively.
Average atomic mass= AtomicmassA×x+AtomicmassA+2×100−x100
⇒A+0.5=Ax+(A+2)(100−x)100
⇒(A+0.5)100=Ax+A100−Ax+200−2x
⇒A100+50=Ax+A100−Ax+200−2x
⇒50=200−2x
⇒2x=200−50
⇒2x=150
∴x=1502=75
x=75%
100−x=25%
Ratio of the percentage abundance of two isotopes=75:25