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Question

Match Column -1 (molecule) with Column - II (shape):
 ColumnI ColumnII(a)P4(p)Crown(b)S8(q)Polymeric (dimeric)(c)AlCl3(r)Tetrahedral(d)PCl5 (s)Trigonal bipyramidal
  1. (a) r;      (b) p;          (c) q;           (d) s
  2. (a) s;      (b) p;          (c) q;           (d) r
  3. (a) r;      (b) q;          (c) p;           (d) s
  4. (a) r;      (b) p;          (c) s;           (d) q


Solution

The correct option is A (a) r;      (b) p;          (c) q;           (d) s

Let us start with each structure: 
Crown sulphur S8 structure
S8 looks like:
Crown sulphur S8 structure
PCl5 looks like:

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