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Coordination Isomerism

Match each co...

Question

Match each coordination compound in List - I with an appropriate pair of characteristics from List - II and select the correct answer using the code given below the lists.
{en = $H_{2} N C H_{2} C H_{2} N H_{2}$ 'atomic numbers; Ti = 22; Cr = 24; Co = 27; Pt = 78}
$\begin{matrix} L i s t I & L i s t I I (P) [C r (N H_{3})_{4} C l_{2}] C l & (1) P a r a m a g n e t i c a n d e x h i b i t s i o n i z a t i o n i s o m e r i s m (Q) [T i (H_{2} O)_{5} C l] (N O_{3})_{2} & (2) D i m a g n e t i c a n d e x i h i b i t s c i s - t r a n s i s o m e r i s m (R) [P t (e n) (N H_{3}) C l] N O_{3} & (3) P a r a m a g n e t i c a n d e x i h i b i t s c i s - t r a n s i s o m e r i s m (S) [C o (N H_{3})_{4} (N O_{3})_{2}] N O_{3} & (4) D i a m a g n e t i c a n d e x i h i b i t s i n o n i z a t i o n i s o m e r i s m \end{matrix}$

A

P - 4, Q - 2, R - 3, S - 1

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B

P - 3, Q - 1, R - 4, S - 2

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C

P - 2, Q - 1, R - 3, S - 4

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D

P - 1, Q - 3, R - 4, S - 2

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Solution

The correct option is B P - 3, Q - 1, R - 4, S - 2
$\begin{matrix} L i s t I & L i s t I I (P) [C r^{111} (N H_{3})_{4} C l_{2}] C l & (1) C o m p l e x g i v e n i n (P) i s p a r a m a g n e t i c (3 u n p a i r e d e l e c t r o n s) & a n d s h o w s t w o g e o m e t r i c a l i s o m e r i s m (c i s a n d t r a n s) (d o e s n o t s h o w i o n i z a t i o n i s o m e r) (Q) [T i^{111} (H_{2} O)_{5} C l] (N O_{3})_{2}] & (2) C o m p l e x g i v e n i n (Q) i s p a r a m a g n e t i c (1 u n p a i r e d e l e c t r o n s) & a n d s h o w s i o n i z a t i o n i s o m e r i s m (R) [P^{11} (e n) (N H_{3}) C l] N O_{3} & (3) C o m p l e x g i v e n i n (R) i s d i a m a g n e t i c (1 u n p a i r e d e l e c t r o n s) & a n d s h o w s i o n i z a t i o n i s o m e r i s m (S) [C o^{111} (N H_{3})_{4} (N O_{3})_{2}] N O_{3} & (4) C o m p l e x g i v e n i n (S) i s d i a m a g n e t i c (0 u n p a i r e d e l e c t r o n s) & a n d d o e s n o t s h o w i n o n i z a t i o n i s o m e r i s m (s h o w g e o m e t r i c a l i s o m e r i s m) \end{matrix}$

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Similar questions

Q. Match each coordination compound in List - I with an appropriate pair of characteristics from List - II and select the correct answer using the code given below the lists.
{en =

H_{2} N C H_{2} C H_{2} N H_{2}

(atomic numbers:

T i = 22; C r = 24; C o = 27; P t = 78

\begin{matrix} L i s t I & L i s t I I (P) [C r (N H_{3})_{4} C l_{2}] C l & (1) P a r a m a g n e t i c a n d e x h i b i t s i o n i z a t i o n i s o m e r i s m (Q) [T i (H_{2} O)_{5} C l] (N O_{3})_{2} & (2) D i a m a g n e t i c a n d e x h i b i t s c i s - t r a n s i s o m e r i s m (R) [P t (e n) (N H_{3}) C l] N O_{3} & (3) P a r a m a g n e t i c a n d e x h i b i t s c i s - t r a n s i s o m e r i s m (S) [C o (N H_{3})_{4} (N O_{3})_{2}] N O_{3} & (4) D i a m a g n e t i c a n d e x h i b i t s i n o n i z a t i o n i s o m e r i s m \end{matrix}

Q. Match each coordination compound in List - I with an appropriate pair of characteristics from List - II and select the correct answer using the code given below the lists.
{en =

H_{2} N C H_{2} C H_{2} N H_{2}

(atomic numbers:

T i = 22; C r = 24; C o = 27; P t = 78

\begin{matrix} L i s t I & L i s t I I (P) [C r (N H_{3})_{4} C l_{2}] C l & (1) P a r a m a g n e t i c a n d e x h i b i t s i o n i z a t i o n i s o m e r i s m (Q) [T i (H_{2} O)_{5} C l] (N O_{3})_{2} & (2) D i a m a g n e t i c a n d e x h i b i t s c i s - t r a n s i s o m e r i s m (R) [P t (e n) (N H_{3}) C l] N O_{3} & (3) P a r a m a g n e t i c a n d e x h i b i t s c i s - t r a n s i s o m e r i s m (S) [C o (N H_{3})_{4} (N O_{3})_{2}] N O_{3} & (4) D i a m a g n e t i c a n d e x h i b i t s i n o n i z a t i o n i s o m e r i s m \end{matrix}

Q. Match each coordination compound in List-I with an appropriate pair of characteristics from List-II and select the correct answer using the code given below the lists. {

e n = H_{2} N C H_{2} C H_{2} N H_{2}

atomic numbers : Ti = 22; Cr = 24; Co = 27; Pt = 78}

List - I	List - II
(P) $[C r (N H_{3})_{4} C l_{2}] C l$	(1) Paramagnetic and exhibits ionisation isomerism
(Q) $[T i (H_{2} O)_{3} C l] (N O_{3})_{2}$	(2) Dimagnetic and exhibits cis-trans isomerism
(R) $[P t (e n) (N H_{3}) C l] N O_{3}$	(3) Paramagnetic and exhibits cis-trans isomerism
(S) $[C o (N H_{3})_{4} (N O_{3})_{2}] N O_{3}$	(4) Dimagnetic and exhibits ionisation isomerism

Q. Match each coordination compound in List-I with an appropriate pair of characteristics from List -II and select the correct the answer using the code given below the lists.

e n = H_{2} N C H_{2} C H_{2} N H_{2}; A t . N o s . : T i = 22; C r = 24; C o = 27; P t = 78

	List - I		List - II
(P)	$[C r (N H_{3})_{4} C l_{2}] C l$	1.	Paramagnetic and exhibits ionisation isomerism.
(Q)	$[T i (H_{2} O)_{5} C l] (N O_{3})_{2}$	2.	Diamagnetic and exhibits cis-trans isomerism
(R)	$[P t (e n) (N H_{3}) C l] N O_{3}$	3.	Paramagnetic and exhibits cis-trans isomerism
(Q)	$[C o (N H_{3})_{4} (N O_{3})_{2}] N O_{3}$	4.	Diamagnetic and exhibits ionisation isomerism

Q. Match each coordination compound in List-I with an appropriate pair of characteristics from List-II and select the correct answer using the code given below the lists.
{

e n = H_{2} N C H_{2} C H_{2} N H_{2};

atomic numbers:

T i = 22; C r = 24; C o = 27; P t = 78

$L i s t - I$	$L i s t - I I$
(P)	$[C r (N H_{3})_{4} C l_{2}] C l$	1.	$Paramagnetic and exhibits ionisation isomerism$
(Q)	$[T i (H_{2} O)_{5} C l] (N O_{3})_{2}$	2.	$Diamagnetic and exhibits cis-trans isomerism$
(R)	$[P t (e n) (N H_{3}) C l] N O_{3}$	3.	$Paramagnetic and exhibits cis-trans isomerism$
(S)	$[C o (C H_{3})_{4} (N O_{3})_{2}] N O_{3}$	4.	$Diamagnetic and exhibits ionisation isomerism$

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