Match each of the compounds in Column I with its characteristic reactions in Column II- begin array - c - - WhlineColumn I - Column IIWhlineA-CH3CH2CH2CN- - PReduction with Pd-C-H2 WhlineB-CH3Ch2OCOCH3- -qReduction with - SnCl2-HClWhlineC-CH3CH-CHCH2OH - rDevelopment 0 of foul - smell - on treatment - with - chloroform - and - alcoholic - KOHWhlineD-CH3CH2CH2CH2NH2 - sReduction with di-isobutylaluminium hydride DIBAL-H- IWhline end array

The correct option is A A p,q ; B s ; C p ; D r[ Column I ...

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Byju's Answer

Standard XII

Chemistry

Stoichiometry

Match each of...

Question

Match each of the compounds in Column I with its characteristic reaction(s) in Column II.
$\begin{matrix} C o l u m n I & C o l u m n I I A . C H_{3} C H_{2} C H_{2} C N : & (P) R e d u c t i o n w i t h P d - C / H_{2} B . C H_{3} C h_{2} O C O C H_{3} : & (q) R e d u c t i o n w i t h S n C l_{2} / H C l C . C H_{3} C H = C H C H_{2} O H & (r) D e v e l o p m e n t o f f o u l s m e l l o n t r e a t m e n t w i t h c h l o r o f o r m a n d a l c o h o l i c K O H D . C H_{3} C H_{2} C H_{2} C H_{2} N H_{2} & (s) R e d u c t i o n w i t h d i - i s o b u t y l a l u m i n i u m h y d r i d e (D I B A L - H) . \end{matrix}$

A-p,q ; B-s ; C-p ; D-r

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A-p,q,s ; B-p,s ; C-p ; D-r

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A-s ; B-p ; C-r ; D-q

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A-q,r ; B-s ; C-p ; D-r,s

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Solution

The correct option is A A-p,q ; B-s ; C-p ; D-r
$\begin{matrix} C o l u m n I & C o l u m n I I A . C H_{3} C H_{2} C H_{2} C N : & G i v e s a m i n e w i t h P d - C / H_{2} G i v e s a l d e h y d e w i t h S n C l_{2} / H C l G i v e s a m i d e w i t h d i - i s o b u t y l - a l u m i n i u m h y d r i d e . G i v e s c a r b o x y l i c a c i d o n a l k a l i n e h y d r o l y s i s B . C H_{3} C h_{2} O C O C H_{3} : & R e d u c e d t o a l c o h o l w i t h P d - C / H_{2} R e d u c e d w i t h d i - i s o b u t y l a l u m i n i u m e s t e r h y d r i d e i n t o a l d e h y d e . U n d e r g o a l k a l i n e h y d r o l y s i s . C . C H_{3} C H = C H C H_{2} O H & R e d u c e d t o b u t a n o l w h e n t r e a t e d w i t h P d - C / H_{2} D . C H_{3} C H_{2} C H_{2} C H_{2} N H_{2} & A p r i m a r y a m i n e, g i v e s c a r b y l a m i n e s t e s t . \end{matrix}$

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