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Question

Match List-I with List-II: Test/Reagents/Observation, Species detected

List-I

Test/Reagents/Observation(s)

List-II

Species detected

(a) Lassaigne’s Test

(i) Carbon

(b) Cu(II) oxide

(ii) Sulphur

(c) Silver nitrate

(iii) N, S, P and halogen

(d) The sodium fusion extract gives black precipitate with acetic acid & lead acetate

(iv) Halogen Specifically


A

(a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)

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B

(a)-(i), (b)-(iv), (c)-(iii), (d)-(ii)

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C

(a)-(iii), (b)-(i), (c)-(ii), (d)-(iv)

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D

(a)-(i), (b)-(ii), (c)-(iv), (d)-(iii)

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Solution

The correct option is A

(a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)


The explanation for correct option:

(A)(a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)

(a)Lassaigne’s Test-(iii) N, S, P and halogen

Lassaigne's test can identify the presence of nitrogen, sulfur, and halogens in organic molecules. Here, the organic compound is heated in a fusion tube together with a little piece of Na metal. The idea is that by doing this, Na changes every element in the vicinity into an ionic form.

Na+C+N=NaCN2Na+S=Na2SNa+X=NaX(X=Cl,Br,orI)

The fused material is boiled with distilled water to release the generated ionic salts. The term for this is sodium fusion extract.

(b)Cu(II) oxide-(i) Carbon

Testing for carbon involves heating a substance with (ii) oxide of copper.

(c )Silver nitrate-(iv) Halogen Specifically

A common test to identify the type of halogen present in a halogenated alkene is the silver nitrate test. Silver nitrate becomes acidic with the addition of dilute nitric acid during the test.

(d) The sodium fusion extract gives a black precipitate with acetic acid & lead acetate-(ii) Sulphur

Acetic acid is used to acidify the sodium fusion extract, and when lead acetate is added, a black precipitate of lead sulfide is formed, indicating the presence of sulfur.

Hence, option (a) is correct.

List (i)List (ii)
(a)Lassaigne’s Test(iii) N, S, P and halogen
(b)Cu(II) oxide(i) Carbon
(c )Silver nitrate(iv) Halogen Specifically
(d) The sodium fusion extract gives a black precipitate with acetic acid & lead acetate(ii) Sulphur

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