No. of radial node =n−l−1 and angular node =l. Total node =n−1 (a) s-orbital ∵r=0,ψ≠0 and 3 radial nodes ⇒4s (b) 3 radial nodes (s,p,d)⇒4s,5px,6dxy (c) Angular probability is dependent of θ and ϕ for 5py,6dxy (d) Atleast one angular node ⇒5px(1);6dxy(2)