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Question

Match List-I with List -II and select the correct answer using the codes given below the lists:
List I (Reaction)List -II (Reagents)

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Solution

The conversion of propene to 2-bromo propane is carried out with HBr. Addition is according to Markownikoff's rule. Bromine is added to more substituted C atom.
The conversion of propene to 1-bromo propane is carried out with HBr in presence of peroxide. Addition is contrary to Markownikoff's rule. Bromine is added to less substituted C atom.
The conversion of propene to 3-bromo-1-propene is carried out with NBS. This is an example of allylic bromination.
The conversion of propene to 1,2-dibromopropane is carried out with NBS.

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