The correct option is
D 1 - C, 2 - A, 3 - B, 4 - D
(1) Heavy water is deuterium oxide
(D2O).
(2) Temporary hardness of water is due to the presence of bicarbonates of Mg and Ca in water. Thus, it is due to the presence of magnesium bicarbonate KgHCO3 and calcium bicarbonate CaHCO3.
(3) Soft water contains no foreign ions.
(4) The permanent hardness of water is due to sulphates and chlorides of Mg and Ca in water. Thus, it is due to the presence of calcium sulphate, magnesium sulphate, calcium chloride and magnesium chloride.