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Question

Match List - I with List - II and select the correct answer using the codes given below the lists:

List-I (Compound)List-II (of Central atom)
(A) [Ni(NH3)6]2+(1) sp3
(B) [PtCl4]2(2) sp3d2
(C) [Ni(CO)4](3) dsp2
(D) [Co(ox)3]3(4) d2sp3

A
(A)2,(B)1,(C)3,(D)4
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B
(A)2,(B)3,(C)1,(D)4
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C
(A)4,(B)1,(C)3,(D)2
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D
(A)4,(B)3,(C)1,(D)2
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Solution

The correct option is B (A)2,(B)3,(C)1,(D)4
[Ni(NH3)6]2+ involves sp3d2 hybridization and has octahedral geometry. It is an outer orbital complex.
[PtCl4]2 involves dsp2 hybridization and has square planar geometry.
[Ni(CO)4] involves sp3 hybridization and has tetrahedral geometry.
[Co(ox)3]3 involves d2sp3 hybridization and has octahdral geometry.It is an inner orbital complex.

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