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Question

Match List-I with List-II.

List-I List-II
Electonic configuration of elements Δ1H (in kJ mol1)
(a) 1s22s2 (i) 801
(b) 1s22s22p4 (ii) 899
(c) 1s22s22p3 (iii) 1314
(d) 1s22s22p1 (iv) 1402

Choose the most appropriate answer from the options given below:

A
(a)(ii),(b)(iii),(c)(iv),(d)(i)
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B
(a)(i),(b)(iv),(c)(iii),(d)(ii)
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C
(a)(iv),(b)(i),(c)(ii),(d)(iii)
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D
(a)(i),(b)(iii),(c)(iv),(d)(ii)
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Solution

The correct option is A (a)(ii),(b)(iii),(c)(iv),(d)(i)
On moving left to right in periodic table, ionisation energy increases (generally) but group-13 elements have lesser I.E. than group-2 elements due to stable ns2 electronic configuration of group-2 elements and group-15 elements have greater I.E. than group-16 elements due to half-filled stable np3 electronic configuration of group-15 elements.
Overall order of I.E should be
c>b>a>d
Hence, D is the correct option.

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