The correct option is D A-4, B-3, C-2, D-1
In C2H6, every carbon is sp3 hybridize so it has 8 hybridize orbitals and 6 pure orbitals.
In C2H4, every carbon is sp2 hybridize so it has 6 hybridize orbitals and 6 pure orbitals.
In C2H2, every carbon is sp hybridize so it has 4 hybridize orbitals and 6 pure orbitals.
In C6H6, every carbon is sp2 hybridize so it has 18 hybridize orbitals and 12 pure orbitals.