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Question

Match the column I with column II amd mark the appropriate choice.

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A
(A) (i) ,(B) (ii), (C) (iii), (D) (iv)
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B
(A) (ii) ,(B) (iii), (C) (iv), (D) (i)
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C
(A) (iii) ,(B) (iv), (C) (i), (D) (ii)
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D
(A) (iv) ,(B) (iii), (C) (ii), (D) (i)
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Solution

The correct option is B (A) (ii) ,(B) (iii), (C) (iv), (D) (i)
A. A reaction of phenol with alkyl chloride in the presence of anhydrous AlCl3 to give ortho and para-substituted phenol is called Friedel craft alkylation reaction.

B. The reaction of phenol with chloroform in basic medium gives CHO group at ortho position in a phenol called salicylaldehyde. The reaction is called Riemer-Tiemann reaction.

C. The reaction of phenol with carbon dioxide in basic medium gives COOH group at ortho position in a phenol called salicylic acid. The reaction is called Kolbe's reaction.

D. The reaction of salicylic acid with hot soda lime (NaOH+CaO) gives phenol. The reaction is called decarboxylation.

(A)- (ii) ,(B)- (iii), (C)- (iv), (D)- (i)

Hence, option B is correct.

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