Match the column I with column II and mark the appropriate choice.
Column I
(Complex) Column II
(Isomerism)
(A) $[C o (N H_{3})_{6}] [C r (C N)_{6}]$ (i) Geometrical isomerism
(B) $[C o (e n)_{2} (N O_{2}) C l] B r$ (ii)
Optical isomerism
(C) $[P t (e n)_{2} C l_{2}]$ (iii) Coordination isomerism
(D) $[C r (C N)_{2} (N H_{3})_{4}]^{2 +}$ (iv) Linkage isomerism

A - (iv), B - (ii), C - (iii), D - (i)

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A - (ii), B - (iii), C - (i), D - (iv)

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A - (iii), B - (iv), C - (ii), D - (i)

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A - (i), B - (iii), C - (iv), D - (ii)

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Solution

The correct option is B A - (iii), B - (iv), C - (ii), D - (i)
$[C O (N H_{3})_{6}] [C r (C N)_{6}] ⟺ [C O (C N)_{6}] [C r (N H_{3})_{6}]$ (Co-ordinate Isomerism)
$[C O (e n)_{2} [N O_{2}] C l] B r \Rightarrow [C O (e n)_{2} (O N O) C l] B r$ (Linkage Isomerism)
$[P t (e n)_{2} C l_{2}]$ (Optical Isomerism)(Refer to image 01)
$[C r (C N)_{2} (N H_{3})_{6}]^{2 +}$ (Refer to image 02)
Geometric Isomerism (Refer to image 03)

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	Column I (Complex)		Column II (Isomerism)
(A)	$[C o (N H_{3})_{6}] [C r (C N)_{6}]$	(i)	Geometrical isomerism
(B)	$[C o (e n)_{2} (N O_{2}) C l] B r$	(ii)	Optical isomerism
(C)	$[P t (e n)_{2} C l_{2}]$	(iii)	Coordination isomerism
(D)	$[C r (C N)_{2} (N H_{3})_{4}]^{2 +}$	(iv)	Linkage isomerism

Match the column I with column II and mark the appropriate choice.Column I(Complex)Column II(Isomerism)(A)[Co(NH3)6][Cr(CN)6](i)Geometrical isomerism(B)[Co(en)2(NO2)Cl]Br(ii)Optical isomerism(C)[Pt(en)2Cl2](iii)Coordination isomerism(D)[Cr(CN)2(NH3)4]2+(iv)Linkage isomerism