Match the column I with column II and mark the appropriate choice.
column I
column II
A
NaH
i
Interstitial hydride
B
CH4
ii
Molecular hydride
C
VH0.56
iii
Ionic hydride
D
B2H6
iv
Electron-deficient hydride
A
(A)→(iii),(B)→(iv),(C)→(ii)(D)→(i)
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B
(A)→(ii),(B)→(iv),(C)→(iii)(D)→(i)
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C
(A)→(i),(B)→(ii),(C)→(iv)(D)→(iii)
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D
(A)→(iii),(B)→(ii),(C)→(i)(D)→(iv)
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Solution
The correct option is D(A)→(iii),(B)→(ii),(C)→(i)(D)→(iv)
NaH is an ionic compound and is made of sodium cations (Na+) and hydride anions (H−). It has the octahedral crystal structure with each sodium ion surrounded by six hydride ions.
CH4 forms molecular or covalent hydrides. These are mainly formed by p - block elements and some s - block elements.
The third compound has an oxidation number of hydrogen which is zero. So it belongs to Interstitial hydride.
In B2H6 the Boron atom is surrounded by 6 electrons, so it is electron deficient due to its incomplete octet.