EAN=Z-X+Y
EAN=Effective atomic number
Z=Atomic number of the metal
X = number of electrons lost during the formation of metal ions from its atom.
Y = number of electrons donated by ligands.
The effective atomic number of the complex [Fe(CO)4]2− is 26+2+8=36.
The effective atomic number of the complex [Co(NH3)5Cl]Cl2 is 27−3+10=36.
The effective atomic number of the complex K2[Ni(CN)4] is 28−2+8=34.
The effective atomic number of the complex [Cu(NH3)4]2+ is 29−2+8=35.