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Question

Match the complexes in column I with the EAN of central atom in column II.

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Solution

EAN=Z-X+Y
EAN=Effective atomic number
Z=Atomic number of the metal
X = number of electrons lost during the formation of metal ions from its atom.
Y = number of electrons donated by ligands.
The effective atomic number of the complex [Fe(CO)4]2 is 26+2+8=36.
The effective atomic number of the complex [Co(NH3)5Cl]Cl2 is 273+10=36.
The effective atomic number of the complex K2[Ni(CN)4] is 282+8=34.
The effective atomic number of the complex [Cu(NH3)4]2+ is 292+8=35.

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