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Question

Match the compounds given in column I with column II and mark the appropriate choice.

Column IColumn II
(A)Benzenesulphonyl chloride(i)Zwitter ion
(B)Sulphanilic acid (ii)Hinsberg reagent
(C)Alkyldiazonium salts (iii)Dyes
(D)Aryldiazonium salts(iv)Conversion to alcohols

A
(A)(iv)(B)(iii)(C)(i)(D)(ii)
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B
(A)(ii)(B)(iv)(C)(iii)(D)(i)
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C
(A)(ii)(B)(i)(C)(iv)(D)(iii)
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D
(A)(ii)(B)(iii)(C)(iv)(D)(i)
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Solution

The correct option is C (A)(ii)(B)(i)(C)(iv)(D)(iii)
(i) Benzene-sulphonyl chloride is the Hinsberg reagent

This is used to distinguish between 1o,2o and 3o amine.
(ii) Sulphanilic acid rearranging to zwitterion

(ii) Alkyl diazonium salts lose nitrogen gas and then treated with water to convert to alcohol.
(iv) Aryl diazonium salts are coupled with aromatic amines/phenol to form dyes.
A) Benzenesulphorylchloride Hinsberg Reagent
B) Sulphanilic Acid zwitterion
C) Alkyldiazonium salts Conversion to alcohols
D) Aryldiazonium Salts Dyes

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