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Question

Match the compounds in column I with their characteristics/test(s)/reagents(s)/stereochemistry given in column II. Matching can be one or more than one.

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Solution

The reagent A is FeCl2
2 moles of cyclopentadine reacts with one mole of ferrous chloride to form one mole of ferrocene.
Phenyl magnesium bromid reacts with oxygen to form phenol.
2PhMgBr(i)ReagentA−−−−−−−−(ii)H3O+2PbOH
Thus, the reagent A is oxygen, O2
Phenyl magnesium bromide reacts with oxygen at low temperature followed by acidification to form benzoic acid.
pHMgBr(i)ReagentAat70oC−−−−−−−−−−−−−−−−−−(ii)H3OPbCOOH
Thus, the reagent A is oxygen, O2.
When tert butyl bromide is heated with neopentane, neopentane is obtained.
Thus, the reagent A is dimethyl zinc.
Me2Zn
When ethyl magnesium bromide is heated with a mixture of CoCl2 and ethyl tosylate, butane is obtained.
C2H5MgBrΔ−−−−−−−ReagentAButane
Thus, the reagent A is a mixture of CoCl2 and EtOTs.

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