The structure of hexamethylenediamine is NH2CH2CH2CH2CH2CH2CH2NH2.
On numbering, the carbons attached to NH2 will get 1st and 6th positions.
The structure of methylethylamine is CH3NHCH2CH3.
o-Toluidine is aniline with a methyl group at the second position of the ring.
Isopropylamine is a propane chain with amino group at the second position.