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Question

Match the crystalline solids in Column-I with packing arrangement in Column-II.

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Solution

(A) CaF2 has a Fluorite structure. Cations have ccp arrangement and anions occupy all the tetrahedral voids.

(B) NaCl has a Rock-Salt structure. Anions have ccp structure and cations occupy all the octahedral voids.

(C) ZnS has a Zinc Blende or Sphelarite structure. Anions have ccp arrangement and cations occupy half of the total octahedral voids.

(D) Na2O has an Antifluorite structure. Anions have ccp arrangement and cations occupy all the tetrahedral voids.

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