Match the detergents given in Column $I$ with their uses given in Column $I I .$

Column I Column II

(i) (a) Dishwashing Powder

(ii) (b) Laundary soap

(iii) $C_{17} H_{35} C O O^{-} N a^{+} + N a_{2} C O_{3} + R o s i n$ (c) Hair conditioners

(iv) $C H_{3} (C H_{2})_{16} C O O^{-} (C H_{2} C H_{2} O)_{12} C H_{2} - C H_{2} O H$ (d) Toothpaste

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Solution

Column I Column II

(i) (c) Hair conditioners

(ii) (d) Toothpaste

(iii) $C_{17} H_{35} C O O^{-} N a^{+} + N a_{2} C O_{3} + R o s i n$ (b) Laundary soap

(iv) $C H_{3} (C H_{2})_{16} C O O^{-} (C H_{2} C H_{2} O)_{12} C H_{2} - C H_{2} O H$ (a) Dishwashing Powder

$(i)$

Hair shampoos/conditioners are made up of cationic detergents. These are quaternary ammonium salts of amines with chlorides, bromides, or acetates, e.g., cetyltrimethylammonium bromide.

$(i i)$

Anionic detergents are used in toothpaste e.g. sodium dodecylbenzenesulphonate. It can be prepared as follows:

$(i i i)$ $C_{17} H_{35} C O O^{-} N a^{+} + N a_{2} C O_{3} + Rosin$

Laundry soaps contain fillers like Sodium Rosinate, Sodium silicate, Borax, and Sodium carbonate. Sodium rosinate makes the soap lather well.

$(i i i) C_{17} H_{35} C O O^{-} N a^{+} + N a_{2} C O_{3} + R o s i n \to$

$(b)$ Laundry soaps

$(i v) C H_{3} (C H_{2})_{16} C O O (C H_{2} C H_{2} O)_{n} C H_{2} C H_{2} O H$

Dishwashing powders are non-ionic detergents, and it can be prepared as:

$C H_{3} (C H_{2})_{16} C O O H + H O (C H_{2} C H_{2} O)_{n} C H_{2} C H_{2} O H - H_{2} O - --- \to C H_{3} (C H_{2})_{16} C O O (C H_{2} C H_{2} O)_{n} C H_{2} C H_{2} O H$
$S t e a r i c a c i d$ $P o l y e t h y l e n e g l y c o l$ $N o n - i o n i c d e t e r g e n t$

$(i v) C H_{3} (C H_{2})_{16} C O O (C H_{2} C H_{2} O)_{n} C H_{2} C H_{2} O H$
$\to Dishwashing powder$

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	Column I		Column II
(i)		(a)	Dishwashing Powder
(ii)		(b)	Laundary soap
(iii)	$C_{17} H_{35} C O O^{-} N a^{+} + N a_{2} C O_{3} + R o s i n$	(c)	Hair conditioners
(iv)	$C H_{3} (C H_{2})_{16} C O O^{-} (C H_{2} C H_{2} O)_{12} C H_{2} - C H_{2} O H$	(d)	Toothpaste

Match the detergents given in Column I with their uses given in Column II. Column I Column II (i) (a) Dishwashing Powder (ii) (b) Laundary soap (iii) C17H35COO−Na++Na2CO3+Rosin (c) Hair conditioners (iv) CH3(CH2)16COO−(CH2CH2O)12CH2−CH2OH (d) Toothpaste