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Question

Match the following:


List - I
List - II
A) Equivalent weight
of KMnO4 in acidic medium
1) M/6
B) KMnO4 in neutral medium
2) M/5
C) KMnO4 in basic medium
3) M/3
D) Phosphorous acid
4) M/2

5) M/1

A
A-2, B-3, C-1, D-5
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B
A-2, B-3, C-5, D-4
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C
A-3, B-2, C-4, D-5
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D
A-3, B-2, C-5, D-4
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Solution

The correct option is A A-2, B-3, C-5, D-4
A. In acidic medium,
Mn+7Mn2+
so, n-factor =5
so, equivalent weight = M5

B. In neutral medium
Mn+7Mn+4
so, n-factor = 3
so, equivalent weight = M3

C. In basic medium,
Mn+7Mn6+
so, n-factor =1
so, equivalent weight = M1

D. Phosphorous acid, have basicity =2,
so, equivalent weight = M2

Option B is correct.

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