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Question

Match the following sets of number of unpaired electrons and magnetic moments.

Set -I Set -II

A) Sc3+ 1) 5, 5.92 B.M

B) V2+ 2) 1, 1.73 B.M.

C) Fe3+ 3) 0, 0 B.M.

D) Cu2+ 4) 3, 3.87 B.M

The correct matching for A B C D is:


A
3 4 1 2
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B
4 1 2 3
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C
3 4 2 1
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D
2 1 3 4
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Solution

The correct option is A 3 4 1 2
Option (A) is correct.
A). Number of unpaired electrons and magnetic moment of Sc3+ is 0 and 0 respectively.
Magnetic moment, μ=n(n+2)
=0(0+2)
=0

B). Number of unpaired electrons and magnetic moment of V2+ is 3 and 3.87 respectively.
Magnetic moment, μ=n(n+2)
=3(3+2)
=3.87 BM

C). Number of unpaired electrons and magnetic moment of Fe3+ is 5 and 5.92 respectively.
Magnetic moment, μ=5(5+2)=5.92 BM
D). Number of unpaired electrons and magnetic moment of Cu2+ is 1 and 1.73 respectively.
Magnetic moment, μ=1(1+2)=1.73 BM

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