Match the hybridization (in List I) with the respective geometrical shape of the hybrid orbitals (in List II).

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Solution

Hybrid Orbital Types in Coordination Compounds
Atomic Orbitals Hybrid type Number of orbitals Structure
s,p $s p$ 2 linear
s,d $s d$ 2 linear
s,p,p $s p^{2}$ 3 trigonal planar
s,p,p,p $s p^{3}$ 4 tetrahedral
s,d,d,d $s d^{3}$ 4 tetrahedral
d,s,p,p $d s p^{2}$ 4 square planar
d,s,p,p,p $d s p^{3}$ 5 trigonal bipyramid
s,p,p,d,d $s p^{2} d^{2}$ 5 square-base pyramid
d,d,s,p,p,p $d^{2} s p^{3}$ 6 octahedral
s,p,p,p,d,d $s p^{3} d^{2}$ 6 octahedral
s,p,d,d,d,d $s p d^{4}$ 6 trigonal prism
s,p,p,p,d,d,d $s p^{3} d^{3}$ 7 pentagonal bipyramid
s,p,p,p,d,d,d,d $s p^{3} d^{4}$ 8 dodecahedron
s,p,p,p,d,d,d,d $s p^{3} d^{4}$ 8 Archimedes antiprism
s,p,p,p,d,d,d,d,d $s p^{3} d^{5}$ 9 capped trigonal prism

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\begin{matrix} LIST-I & LIST-II P . d s p^{2} & 1. [F e F_{6}]^{4 -} Q . s p^{3} & 2. [T i (H_{2} O)_{3} C l_{3}] R . s p^{3} d^{2} & 3. [C r (N H_{3})_{6}]^{3 +} S . d^{2} s p^{3} & 4. [F e C l_{4}]^{2 -} 5. N i (C O)_{4} 6. [N i (C N)_{4}]^{2 -} \end{matrix}

S F_{4}

s p^{3} d^{2}

I F_{5}

d^{2} s p^{3}

N O_{2}^{+}

s p^{3} d

N H_{4}^{+}

s p^{3}

s p

\begin{matrix} L i s t - I & L i s t - I I (p) [N i (C N)_{4}]^{2 -} & (1) s p^{3} h y b r i d i z a t i o n (Q) [N i (C O)_{4}] & (2) d s p^{2} h y b r i d i z a t i o n (R) [C u (N H_{3})_{4}]^{2 +} & (3) μ = 0 B M (S) [P d (C l)_{4}]^{2 -} & (4) μ = 1.732 B M \end{matrix}

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